Abstract
The examination of a solution of bromine chloride in hydrochloric acid by ultra-violet absorption and redox potential measurements has demonstrated the existence in these solutions of a complex ion of formula BrCl 6 5−, with a stability constant of (2·6 1·0) × 10 2. The formulae of the similar complex ions formed from iodine chloride and bromide were shown to be ICl 6 5− and IBr 4 3− with stability constants (4·3 ± 2·2) × 10 2 and (5·0 ± 1·0) × 10 2. The experimental procedure was shown to be correct by an investigation of the I 3 − complex.
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