Abstract
The comparative investigation of the electrochemical reduction of a number of pyridylporphyrin derivatives with alkyl substituents and their cobalt(II) complexes in 0.1 M KOH is carried out by cyclic voltammetry (CV). The influence of isomerism of the porphyrin molecule and the nature of metal on the oxidative capacity of the tetrapyrrole macrocycle and on the electrocatalytic activity of compounds studied for the oxygen electroreduction reaction is established.
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