In situ study of flow accelerated corrosion and its mitigation at different locations of a gradual contraction of N80 steel

Abstract

A gradual pipe contraction may cause severe localized corrosion resulted from the flow acceleration, thus threating the operating safety of pipelines in the oil and gas field. Until now, the quantitative study on the correlation between local corrosion rate and local hydrodynamics at the gradual pipe contraction is still missing.In this work, the flow accelerated corrosion and its mitigation at different locations of a gradual pipe contraction of N80 steel are in situ investigated using computational fluid dynamics simulation and array electrode technique combined with electrochemical impedance spectroscopy. The results show that the distribution of corrosion rate at the gradual pipe contraction is in good accordance with the distribution of hydrodynamics parameters including flow velocity and wall shear stress, i.e., the higher flow velocity or higher wall shear stress is, the higher local corrosion rate is. The presence of an imidazoline derivative inhibitor can greatly mitigate the corrosion at the gradual pipe contraction through hindering the mass transfer process and charge transfer process of corrosion. Furthermore, in the presence of inhibitor the differences in corrosion rate among different locations at the gradual pipe contraction are also effectively reduced, or even disappeared at low flow velocity. Therefore, the addition of the inhibitor is an effective way to mitigate or even eliminate the flow accelerated corrosion at the gradual pipe contraction in the oil and gas field.