Abstract
In(III)‐Catalyzed O‐annulation of cyclic diazodicarbonyl compounds with 2‐naphthols, 6‐quinolinol, β‐tetralone, and 9‐phenanthrol is developed. This novel synthetic strategy paves a facile and desired access to diverse and functionalized benzochromones. This imperative protocol involves domino carbene generation, ketene formation through Wolff‐rearrangement, nucleophilic addition, H‐migration, intramolecular cyclization, and elimination of water.
Published Version
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