Improved performance of polyamide nanofiltration membrane embedded with zeolite beta

Abstract

In this study, zeolite beta nanoparticles were incorporated into an interfacial polymerization procedure for the fabrication of thin film nanocomposites (TFNs). The successful introduction of zeolite beta into the polyamide (PA) selective layer was confirmed by surface attenuated total reflection infrared spectroscopy (ATR-FTIR), and x-ray photoelectron spectroscopy (XPS). The introduction of porous structured zeolite beta improved the water flux and rejection rate of the TFN membrane compared to the PA thin film composite (TFC) membrane. A quantitative performance coefficient is further proposed in this work, comprehensively considering the flux and rejection rate to evaluate the performance of TFNs. For five salt solutions, we found that the TFN0.3 membrane with 0.3 wt% of zeolite particles had a high coefficient of performance. With the help of zeolite particles, the TFN0.3 membrane achieved a high flux of 92.53 L/(m2·h) under an operating pressure of 5 bar. For ion separation from binary solutions, the TFN0.2 membrane with 0.2 wt% zeolite content was a better choice for a wide range of binary mixtures, which is because the addition of zeolite beta resulted in smaller pore sizes, the strongest zeta potential, and the thickest thickness (scanning electron microscope, SEM determined) of the TFN0.2 membrane. All these factors contribute to the selectivity of the TFN0.2 membrane. Our study provides an efficient and cost-effective method to simultaneously improve the permeability and rejection of nanofiltration membranes, facilitating the development of nanofiltration for water recovery.