Interfacial polymerization on PES hollow fiber membranes using mixed diamines for nanofiltration removal of salts containing oxyanions and ferric ions

Abstract

Thin film composite (TFC) hollow fiber nanofiltration (NF) membranes were fabricated via interfacial polymerization, with mixed diamines of piperazine (PIP) and 2,2′-bis(1-hydroxyl-1-trifluoromethyl-2,2,2-triflutoethyl)-4,4′-methylenedianiline (BHTTM) as water phase and trimesoyl chloride (TMC) as organic phase. Fabricated membranes were characterized for ATR-FTIR, SEM, AFM, and water contact angle. Formation conditions of the selective polyamide layer have been optimized for a good NF membrane performance. The pure water flux of NF membrane prepared under optimized conditions was 31.2L·m−2·h−1 and the rejection for Na2SO4 was 99.7% at 6bar. The rejections of NF membranes for different salts followed the order: Na2SO4>MgSO4>NaCl>MgCl2. The molecular weight cut-off of NF membrane was around 300Da. The performance of NF membranes was stable during a 7-day filtration process for rejecting different species ions including heavy metal ferric ion (FeCl3 and Fe2(SO4)3) and oxyanions (SO42− and HPO42−), in addition to different inorganic salts. Also, the NF membranes exhibited chlorine tolerant property. This work demonstrates the potential of PES outer-selective TFC hollow fiber membranes for desalination or water softening process, provides database to fabricate suitable NF membranes for long-term salts removal and raise a simple technique to form a thin chlorine-tolerant polyamide layer.