Abstract

The hydrogen storage properties of LiBH4 ball milled with various ratios of carbon nanotubes (Cnano) were investigated. The LiBH4∕Cnano mixtures showed superior dehydrogenation, hydrogen desorption starting at 250°C, and the majority of hydrogen being released below 600°C. The rehydrogenation results revealed that the Li2C2, formed during the dehydrogenation, could be reversed to LiH, in which the hydrogen capacity corresponds to 1∕4 of the original hydrogen content of LiBH4, and C at 10MPa hydrogen pressure and 400°C.

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