Abstract

Diamond-like carbon films were deposited from methane gas by ion beam deposition. The hydrogen content and bonding structure of the films were studied as a function of deposition conditions. The hydrogen concentration was measured by elastic recoil detection analysis with a 50 MeV Ar ion beam and the bonding structure determined by IR and Raman spectroscopy. The hydrogen content of the carbon films is 20–30 at%. The hydrogen plays an important role in forming the bonding structure of the films and affects the mechanical properties of the films. Both hydrogen content and bonding structure are shown to depend on the substrate temperature and the bias voltage applied to the substrate.

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