Hydration, strength, and microstructure evolution of Portland cement-calcium sulphoaluminate cement-CSH seeds ultra-early strength cementitious system

Abstract

Improving the very early age strength of precast concrete components at ambient temperature and ensuring the development of later strength is of significant engineering importance. This objective was successfully achieved by incorporating a specific percentage of 0–3% CSH seeds (CSHs) and 5%-20% calcium sulphoaluminate cement (CSA) into Portland cement (PC). The hydration, strength and microstructure evolution of Portland cement-calcium sulphoaluminate cement-CSH seeds cementitious system were investigated. Hydration heat tests reveal that CSHs effectively accelerated the early hydration of the slurry within the first 12 h without affecting its later hydration. CSHs and CSA acted synergistically to enhance hydration kinetics. However, it is crucial to control the proportion of CSA within the range of 5%-10%; exceeding this ratio can severely inhibit the hydration of silicates. Strength tests indicate that the addition of CSHs and CSA can increase the compressive and flexural strengths of mortar within the first 12 h by 282% and 208%, respectively, without impacting the development of its later-age strength. Together, they synergistically provide favorable support for the strength and toughness of matrix. Based on linear regression analysis and nitrogen adsorption and desorption tests, it was concluded that CSHs enhance the hydration dependence of matrix strength, while CSA diminishes this characteristic. This is because CSHs refine the pore size distribution of the paste, increasing the proportion of micropores, whereas CSA promotes the formation of more mesopores and macropores, leading to coarser pores; however, 5% CSA is beneficial for further refining the pore structure. The microcosmic phase evolution of the early-strength cementitious system was analyzed through X-ray diffraction and scanning electron microscope-energy dispersive spectrometer experiments. Results demonstrate that low proportions of CSA and CSHs promote the co-growth of ettringite and C-S-H gel, ensuring a more rapid formation of a dense hydration network in the early stages, thereby accelerating strength development. These findings provide a reference for the design and preparation of precast concrete.