Abstract

Zinc oxide (ZnO) porous-shell hollow spheres (PHS) were prepared by thermally oxidizing high-purity zinc powder in an oxygen-containing atmosphere, and its ethanol gas sensing properties were measured in the concentration range of 10–400ppm. At the optimum operating temperature of 350°C, a sensitivity of 0.25/ppm was obtained and the response–concentration curve was of high linearity. The response and recovery times were measured to be ∼5–12s and 8–13s, respectively. The sensor was proved to be highly selective to ethanol. Our results indicate that ZnO PHS might be a promising material for fabricating practical ethanol sensors.

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