Experimental analysis of UV-activated ethanol sensor based on the formation of organic/inorganic heterojunction

Abstract

PurposeThe purpose of this paper is to fabricate an ethanol sensor which has bio-friendly and eco-friendly properties compared to the commercially available ethanol sensors.Design/methodology/approachThis paper describes the construction of a highly sensitive ethanol sensor with low ppm level detection at room temperature by integrating three techniques. The first deals with the formation of organic/inorganic p-n heterojunction. Second, tuning of structural parameters such as length, diameter and density of Zinc Oxide (ZnO) nanostructure was achieved through introduction of the Fe dopant into a pure ZnO seed layer. Furthermore, ultra-violet (UV) light photoactivation approach was used for enhancing the sensing performance of the fabricated sensors. Four different sensors were fabricated by combing the above approaches. The structural, morphological, optical and material compositions were characterized using different characterization techniques. Sensing behavior of the fabricated sensors toward ethanol was experimented at room temperature with and without UV illumination combined with stability studies. It was observed that all the fabricated sensors showed enhanced sensing performance for 10 ppm of ethanol. In specific, FNZ (Fe-doped ZnO seeded Ni-doped Zn nanorods) sensor exhibited a higher response at 2.2 and 13.5 s for 5 ppm and 100 ppm of ethanol with UV light illumination at room temperature, respectively. The photoactivated FNZ sensor showed quick response and speedy recovery at 18 and 30 s, respectively, for 100 ppm ethanol.FindingsIn this study, the authors have experimentally analyzed the effect of Fe (in ZnO seed layer and ZnO NRs) and Ni (in ZnO NRs) dopants in the room temperature sensing performance (with and without UV light) of the fabricated ethanol sensors. Important sensing parameters like sensitivity, recovery and response time of all the fabricated sensors are reported.Originality/valueThe Fe doped ZnO seeded Ni doped Zn nanorods (FNZ sample) showed a higher response at 2.2 s and 13.5 s for very low 5 ppm and 10 ppm of ethanol at room temperature under UV light illumination when compared to the other fabricated sensors in this paper. Similarly, this sensor also had quick response (18 s) and speedy recovery (30 s) for 100 ppm ethanol.