Abstract
Wave functions which are compact, but still quite accurate, are extremely valuable as tools for gaining understanding of quantum systems. This paper investigates the use for that purpose of functions that depend exponentially on all the interparticle distances of a few-body system, illustrated by a study of the ground electronic states of the He isoelectronic series (Z from 1 to 10). Using as few as 4 exponential basis functions, it is found that nonrelativistic energies are reproduced to within 38 microhartrees of the exact values, an error far less than for previously reported compact wave functions. Other properties are also well-represented.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.