Abstract

Oxidation behavior of two ferrite/martensite(F/M) steels, namely a novel 9%-12% Cr modified F/M steel(SIMP steel) and a commercial T91 steel were comparatively studied in air at 800 oC. The oxide scales formed on the two steels were characterized by XRD, SEM and EPMA. The results show that the oxide scale formed on SIMP steel is single- layer composed of Cr_2O_3 and Mn_(1.5)Cr_(1.5)O_4 spinel particles,and Si was enriched at the interface between the chromia scale and matrix; while the oxide scale formed on T91 steel has a double layered structure with an outer hematite Fe_2O_3 layer and an inner Fe-Cr spinel layer. The SIMP steel has better high temperature oxidation resistance than T91 steel, which may be due to the higher content of Cr and Si beneficial to the formation of the compact oxide scale on the SIMP steel.

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