Graphene cladded cobalt phosphide nanoparticles with a sandwich structure by plasma for lithium and sodium storage.

Abstract

Graphene cladded cobalt phosphide nanoparticles with a sandwich structure are synthesized using Ar-H2-P plasma. In situ phosphorization and graphene reduction are achieved at the same time. Benefitting from the sandwich structure and heterointerface between CoP and RGO, the electrode delivered a high reversible capacity and durable lifespan for both lithium and sodium storage.