Grain size stabilization of nanocrystalline copper at high temperatures by alloying with tantalum

Abstract

Nanocrystalline Cu–Ta alloys belong to an emerging class of immiscible materials with potential for high-temperature applications. Differential scanning calorimetry (DSC), Vickers microhardness, transmission and scanning electron microscopy (TEM/SEM), and atomistic simulations have been applied to study the structural evolution in high-energy cryogenically alloyed nanocrystalline Cu–10at.%Ta. The thermally induced coarsening of the as-milled microstructure was investigated and it was found that the onset of grain growth occurs at temperatures higher than that for pure nanocrystalline Cu. The total heat release associated with grain growth was 0.553kJ/mol. Interestingly, nanocrystalline Cu–10at.%Ta maintains a mean grain size (GS) of 167nm after annealing at 97% of its melting point. The increased microstructural stability is attributed to a combination of thermodynamic and kinetic stabilization effects which, in turn, appear to be controlled by segregation and diffusion of Ta solute atoms along grain boundaries (GBs). The as-milled nanocrystalline Cu–10at.%Ta exhibits Vickers microhardness values near 5GPa surpassing the microhardness of conventional pure nanocrystalline Cu by ∼2.5GPa.