Abstract

The results of an infrared and Raman spectroscopic study are reported for seven new metal(II) 8-hydroxyquinoline tetracyanonickelate complexes, M(8-HQ) 2 Ni(CN) 4 [where (8-HQ) = 8-hydroxyquinoline; M = Mn, Fe, Co, Zn, Ni, Cu or Cd]. Spectroscopic and magnetic susceptibility measurements indicate that the compounds have the structure of Hofmann-type complexes. The copper complex has spectral features different from the other six compounds.

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