Formation of microcrystalline silicon and SiN x films by electron-beam-induced-chemical vapor deposition at ultra low temperature

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Abstract We synthesized silicon films (hydrogenated microcrystalline silicon in hydrogenated amorphous silicon) and silicon nitride films by electron-beam-induced-chemical vapor deposition combined with low-temperature H tunneling reactions on cooled substrates, which adsorb source gases (SiH 4 or Si 2 H 6 ). The photoconductivity of the silicon film was 0.7 × 10 − 5 Ω − 1 cm − 1 and the dark conductivity was 3.3 × 10 − 5 Ω − 1 cm − 1 . The dielectric constant of the silicon nitride film was estimated to be 6.5–7.0.