Formation of acidic Brönsted (MoOx)−(Hy)+ evidenced by XRD and 2,6-lutidine FTIR spectroscopy for cumene cracking

Abstract

2,6-Lutidine adsorbed IR spectroscopy has been employed to study the property of acidic sites on MoO3 and Pt/MoO3. The results showed that both catalysts possess doublet adsorption bands at 1605+1585cm−1, ascribed to Lewis acid sites, and duo-doublet bands at 1660+1650 and 1640+1630cm−1, ascribed to hydroxyl groups; these indicate an OH defect structure of MoO3 and Mo–OH Brönsted acidic sites. All Brönsted acid sites were strong enough to retain outgassing at 473K, while a considerable number of relatively weak and medium acid sites as well as strong Lewis acid sites existed. The addition of Pt slightly altered the ratio of Lewis/Brönsted acid sites and distribution of Lewis acid sites. The XRD result confirmed the formation of molybdenum oxyhydride (MoOx)−(Hy)+ on the hydrogen treated Pt/MoO3, whereas the hydrogen adsorption on 2,6-lutidine pre-adsorbed catalysts showed the formation of protonic acid sites over Pt/MoO3. These results strongly suggested that the interaction of molecular hydrogen with Pt/MoO3 formed acidic Brönsted (MoOx)−(Hy)+ via a hydrogen spillover mechanism. In fact, no (MoOx)−(Hy)+ and protonic acid sites were observed on Pt-free MoO3. The presence of (MoOx)−(Hy)+ enhanced the activity of Pt/MoO3 in the cumene hydrocracking in which the rate conversion of cumene increased by about 30%, while the apparent activation energy decreased by approximately 28kJ/mol.