Fluorescence amplification in laser-pumped random media: Fundamental limitations

Abstract

Experimental data on the narrowing of fluorescence spectra of laser-pumped random media are interpreted within the framework of a probabilistic model of incoherent amplification of the stimulated component of fluorescence. R6G- and DCM-doped layers of dense-packed anatase and anatase-rutile particles and suspensions of DCM crystallites were examined under pulse-periodic laser pumping with various pump intensities at the wavelength of 532 nm. It was shown that, in the case of quasi-stationary fluorescence response at high pump intensities, amplification of stochastically propagating partial components of fluorescence field at various wavelengths is governed by the pump-independent factor of fluorescence amplification and the average number of stimulated emission acts in the pumped system. Analysis of the experimental data has shown that, despite certain simplifying assumptions, the considered model reasonably describes evolution of the fluorescence spectra of random fluorescent media with the increase in the pump intensity. A procedure of recovery of the fluorescence amplification factor from the sets of fluorescence spectra obtained at various pump intensities is considered. Features of the spectral shapes of the recovered amplification factors caused by the influence of the scattering matrices in pumped media are discussed.