Abstract

The objective of the present work is to investigate the full phase diagram of a binary system composed of carbon dioxide and a heavy paraffin. An alkane with an odd carbon number was chosen since mixtures of paraffins crystallize in the orthorhombic structure like pure odd paraffins do. The normal-heptadecane was taken into consideration for this study as it has a melting temperature close to the ambient condition (295 K). The work consists in measuring both fluid phase equilibria and fluid-solid phase transition conditions. The measurement of liquid-vapor and liquid-liquid phase transition in the temperature range 273 - 363 K has been made as well as the measurements of solid crystallization up to 70 MPa. The influence of carbon dioxide content has been studied from 0 to 99%.

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