Flash Nitrogen-Doped Carbon Nanotubes for Energy Storage and Conversion.

Abstract

In recent years, nitrogen-doped carbons show great application potentials in the fields of electrochemical energy storage and conversion. Here, the ultrafast and green preparation of nitrogen-doped carbon nanotubes (N-CNTs) via an efficient flash Joule heating method is reported. The precursor of 1D core-shell structure of CNT@polyaniline is first synthesized using an in situ polymerization method and then rapidly conversed into N-CNTs at ≈1300 K within 1 s. Electrochemical tests reveal the desirable capacitive property and oxygen catalytic activity of the optimized N-CNT material. It delivers an improved area capacitance of 101.7 mF cm-2 at 5mV s-1 in 1m KOH electrolyte, and the assembled symmetrical supercapacitor shows an energy density of 1.03 µWh cm-2 and excellent cycle stability over 10000 cycles. In addition, the flash N-CNTs exhibit impressive catalytic performance toward oxygen reduction reaction with a half-wave potential of 0.8V in alkaline medium, comparable to the sample prepared by the conventional long-time pyrolysis method. The Zn-air battery presents superior charge-discharge ability and long-term durability relative to commercial Pt/C catalyst. These remarkable electrochemical performances validate the superiorities of the Joule heating method in preparing the heteroatom-doped carbon materials for wide applications.