Abstract
The ceramic-metal interface is present in various material structures and devices that are vulnerable to failures, like cracking, which are typically due to their incompatible properties, e.g., thermal expansion mismatch. In failure of these multilayer systems, interfacial shear strength is a good measure of the robustness of interfaces, especially for planar films. There is a widely-used shear lag model and method by Agrawal and Raj to analyse and measure the interfacial shear strength of thin brittle film on ductile substrates. The use of this classical model for a type of polymer derived ceramic coatings (thickness ~18 μm) on steel substrate leads to high values of interfacial shear strength. Here, we present finite element simulations for such a coating system when it is subjected to in-plane tension. Results show that the in-plane stresses in the coating are non-uniform, i.e., varying across the thickness of the film. Therefore, they do not meet one of the basic assumptions of the classical model: uniform in-plane stress. Furthermore, effects of three significant parameters, film thickness, crack spacing, and Young’s modulus, on the in-plane stress distribution have also been investigated. ‘Thickness-averaged In-plane Stress’ (TIS), a new failure criterion, is proposed for estimating the interfacial shear strength, which leads to a more realistic estimation of the tensile strength and interfacial shear strength of thick brittle films/coatings on ductile substrates.
Highlights
Ceramics, including ceramic matrix composites (CMC), are often used together with metallic components in various industrial applications
Once the finite element method (FEM) model is set up (Section 4), several key parameters can be assigned with real values for both substrate and film layers, including the Young’s moduli of both materials, film thickness, and crack spacing
The simulated in-plane stress distribution in the film is shown in Figures 2 and 3
Summary
Ceramics, including ceramic matrix composites (CMC), are often used together with metallic components in various industrial applications. Ceramic coatings made from polymer derived ceramics (PDCs) [1,2,3] have been investigated recently as a promising environmental barrier coating system at high temperatures [4,5,6,7,8,9]. The interface, which was created by the direct bonding between the ceramic and metallic substrate, is a critical element and potential failure location in such multilayer structures. It is important to measure and understand the failure mechanism of such interfaces so that coating material’s processing and structure can be optimized.
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