Fabrication of a Cu(II)-Selective Electrode in the Polyvinyl Chloride Matrix Utilizing Mechanochemically Synthesized Rhodamine 6g as an Ionophore.

Abstract

A Cu(II)-selective electrode has been fabricated by utilizing a mechanochemically synthesized copper-specific ionophore “L” embedded in a poly(vinyl chloride) membrane. 2-Nitrophenyloctylether and sodium tetraphenylborate have been used as a plasticizer and as a solvent mediator, respectively, and found to be enhancing the sensitivity of the fabricated ion-selective electrode (ISE). A range of membranes (S1–S7) with varying compositions were casted and investigated in ISE. Results revealed an excellent Nernstian response of 29.38 ± 0.55 mV/dec for the ISE S6. The fabricated ISE operates well in the pH window 4.0–7.5, and the limit of detection was found to be 5 μM (0.3 ppm). Quick response time (15 s), long shelf-life, and selectivity (on the order of 10–4 and 10–5) over a number of interfering cations enabled S6 promising for real off laboratory sample analysis and can be employed to detect copper ion in various industrial as well as biological and environmental samples. To demonstrate the practical application of these ISE, the Cu concentration in the digested printed circuit board has been estimated using the standard calibration plot. The fabricated ISE has been regenerated through extracting copper by chelating with ethylenediaminetetraacetic acid.