Abstract

This paper presents the fabrication and characterization of various sets of gate stacks: n-Si/SiO2/ALD-HfO 2 /Ti-Pt, n-Si/SiON/ALD-HfO 2 /Ti-Pt, n-Si/SiON/ALD-ZrO 2 /Ti-Pt and n-Si/SiON/ALD-ZrON/Ti-Pt under N2 and NH3 as annealing ambients. The XRD, AFM and FTIR characterizations have been performed for their structural and morphological studies; whereas the electrical characterization includes capacitance-voltage (C-V), conductance-voltage (G-V) and current-voltage (I-V) analysis. Electrical parameters such as dielectric constant (k), effective oxide thickness (EOT) and leakage current density (J) have been extracted through C-V, G-V and I-V measurements. The results suggest that SiON growth prior to HfO 2 , ZrO 2 and ZrON deposition has the potential to surmount the problem of high leakage current density and interfacial traps due to sufficient amount of N 2 incorporated at their interface. Electrical characterization such as C-V and I-V reveals the improved results for NH3 annealed ZrO 2 sample relative to the all other samples in terms of suppressed gate leakage current, increased dielectric constant and reduced EOT.

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