Abstract
Roth H., Peters-Gerth P. and Lucas K., 1992. Experimental vapor-liquid equilibria in the systems R 22-R 23, R 22-CO 2, CS 2-R 22, R 23-CO 2, CS 2-R 23 and their correlation by equations of state. Fluid Phase Equilibria, 73: 147-166. Vapor-liquid equilibria in systems with polar molecules tend to show a rather complex phase behavior. In order to investigate the phase boundaries in mixtures of dipolar and quadrupolar components five binary systems of the components R 22, R 23, CO 2 and CS 2 have been selected. Experimental VLE data for the systems R 22-R 23, R 22-CO 2, CS 2-R 22, R 23-CO 2 and CS 2-R 23 are reported in this paper at temperatures between 254 and 473 K and pressures up to 25 MPa. The data were correlated with one empirical and one semi-empirical equation of state.
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