Experimental determination of the constitutive properties of a graphite anode layer in lithium-ion batteries using a bending test method

Abstract

The stress-strain relationship of a dry lithium-ion graphite anode coating has been characterized by a bending test method. The method is based on U-shaped bending of single-side coated electrodes, which enables separate measurements of tensile and compressive properties of the electrode coating. The experiments reveal that the elastic modulus of the anode coating in compression is higher than the elastic modulus in tension and that the compressive stiffness increases with strain level. Contrary, the tensile modulus is approximately independent of strain. The quantitative results for compressive modulus, and in particular the stiffening effect with increasing strain, are believed to be new to the battery research community. The measured stiffness of the anode coating is compared to previously reported results for a cathode coating. It is found that the anode coating is stiffer in compression compared to the cathode coating despite a much larger particle stiffness of the cathode material in comparison to the anode. It is concluded that differences in porosity are the main reason for the observed behavior. The method also successfully captures the hysteresis effects, both in tension and compression, that are present due to the polymeric binder and the evolution of microstructural contacts. Relaxation experiments are as well conducted to characterize the time-dependent properties of the anode coating, and the response is modeled by a Prony series.