Abstract

This paper assessed and evaluated the river and groundwater quality of five major catchments in the Mzimvubu to Tsitsikamma Water Management Area (WMA7). The river assessment and evaluation considered the present state maximum, minimum and mean seasonal values of physiochemical parameters (EC, NO3 + NO2, Cl, pH, NH4-N, PO4-P and Mg). The study was able to successfully make use of statistical analysis and a water quality index in order to explain seven-year trends and the present state of all five catchments within the study area. The statistical analysis results showed that water quality parameters such as PO4, NH4 and NO3 + NO2 were not complying with the South African Water Quality Guidelines (SAWQG) limits, suggesting that the study area was impacted by anthropogenic activities such as agriculture, sewage works, etc. The application of WQI showed that the Gamtoos catchment was in a good water quality state (49.71) while the other four catchments were in a poor to very poor state, according to the WQI classification. Based on the groundwater quality assessment, the physicochemical parameters (NH4, EC, Ca, NO3 + NO2, pH, Na, Cl, Mg, F, K, SO4 and CaCO3) were selected and the main parameters of concern were EC (salinity), NO3 + NO2 and SO4. However, groundwater assessment revealed that groundwater quality was chemically suitable for drinking purposes in most parts of the study area. Therefore, the study recommended resource-directed measures to improve surface and groundwater resource protection, especially in areas where surface and groundwater quality for other uses remains a challenge. Further, strong water resource compliance monitoring and enforcement to control water resource pollution sources is critical.

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