Year-end Sale % OFF 
Abstract
Equilibria of the reaction of copper(II) acetate with perchloric acid and lithium acetate were investigated by spectrophotometry. The reaction of copper(II) acetate with perchloric acid is written as follows: Cu 2( OAc) 4 + 2 HClO 4 ⇌ β 11 2 Cu( OAc)( ClO 4) + 2 HOAc Cu 2( OAc) 4 + 4 HClO 4 ⇌ β 12 2 Cu( ClO 4) 2 + 4 HOAc where HOAc denotes acetic acid. Overall formation constants of the complexes are determined as log β 11 = 3·5 ± 0·1 and log β 12 = 10·4 ± 0·1. Equilibria of copper(II) acetate with lithium acetate are written as follows: Cu 2( OAc) 4 + 2 LiOAc ⇌ β 26 Li 2 Cu 2( OAc) 6 Cu 2( OAc) 4 + 4 LiOAc ⇌ β 14 2 Li 2 Cu( OAc) 4 Overall formation constants of the complexes are given as log β 26 = 0·89 ± 0·05 and log β 14 = − 0· ± 0·1.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
