Abstract
The solid—solid interactions of uranyl nitrate—thiourea in closed reaction vessels are studied by DSC. The thiourea (Th) appears able to coordinate with uranyl ion, in the absence of the solvent, to form complexes in which the Th molecules are more than two. The associated enthalpic values are evaluated from DSC curves and the results are briefly compared with those obtained using urea or phenylurea as neutral ligands.
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