Abstract
The infiltration technique is a cost-effective method to develop nanostructured electrodes that can accelerate sluggish oxygen reduction reaction (ORR) and enhance the electrochemical performance of solid oxide fuel cells (SOFCs) at intermediate temperatures (600-800 °C). For metal-supported SOFCs, identifying a highly efficient ORR catalyst is an ongoing challenge due to lower temperature operation. In this work, nanostructured praseodymium oxide (PrOx) and multiphase heterostructures containing perovskites with the nominal composition of Nd0.6Sr0.4CoO3-δ (NSC), SrCO3, and CoO have been developed via infiltration into the symmetric metal-supported backbone as binary layer composite, and their electrochemical performance has been investigated. The composite demonstrates enhanced electrochemical performance at various temperatures achieving the lowest polarization resistance (Rp) of 0.05 Ω cm2 at 700 °C compared to multiphase NSC alone (0.1 Ω cm2) under similar conditions. A distribution function of relaxation time (DFRT) analysis using impedance spectroscopy genetic program (ISGP) was carried out to study different electrochemical processes. PrOx significantly improves the processes involved in the ORR. The full cell performance of the composite electrode achieves a peak power density (PPD) of 329 mW·cm-2 at 700 °C in 3%H2O/H2 as fuel.
Published Version
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