Energy efficiency of membrane distillation: Simplified analysis, heat recovery, and the use of waste-heat

Abstract

Membrane distillation (MD) is a thermal desalination process that is advantageous due to its ability to harness low-grade waste heat to separate highly saline feedstock. However, like any thermal desalination process, the energy efficiency depends on the ability to recover latent heat from condensation in the distillate. In direct contact MD (DCMD), this can be achieved by integrating a heat exchanger (HX) to recover latent heat stored in the distillate stream to preheat the incoming feed stream. Based on the principle of equal heat capacity flows, we derive a simple and intuitive expression for the optimal flow rate ratio between the feed and distillate streams to best recover this latent. Following the principle of energy balance, we derive simple expressions for the specific thermal energy consumption (SECth) and gained output ratio (GOR) of DCMD with and without a coupled HX for latent heat recovery, revealing an intuitive critical condition that indicates whether DCMD should or should not be coupled with HX. As MD is attractive for its ability to use low-grade waste heat as a heat source, we also evaluate the energy efficiency of DCMD powered by a waste heat stream. A waste heat stream differs fundamentally from a conventional constant-temperature heat source in that the temperature of the waste heat stream decreases as heat is extracted from it. We discuss the implication of this fundamental difference on energy efficiency and how we should analyze the energy efficiency of DCMD powered by waste heat streams. A new metric, namely specific yield, is proposed to quantify the performance of DCMD powered by waste heat stream. Our analysis suggests that, for a single-stage DCMD powered by a waste heat stream, whether implementing latent heat recovery or not only affects conventional metrics for energy efficiency (e.g. SECth and GOR) but not the specific yield. Overall, this analysis presents an intuitive and important framework for evaluating and optimizing energy efficiency in DCMD.