Abstract

Proton ENDOR investigations of the thermally stable VO 2+ complex in ferroelectric triglycine sulphate single crystals are reported. Magnetic hyperfine coupling constants of the ligand protons of the amino and methylene groups are given and discussed. The ENDOR investigations confirm the conclusion derived from EPR studies that the vanadyl ion occupies an interstitial lattice site forming a bis(glycinato) VO(II) complex with triclinic symmetry C 1.

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