Abstract
There is a growing demand for heavy metal removal by membrane technology in real applications. However, few studies were reported concerning antimony (Sb) removal by membrane technology. Herein, a novel thin film nanocomposite (TFN) membrane comprising an alginate (SA) selective layer and a polyether sulfone (PSF) support membrane incorporating chitosan functionalized iron nanocomposite has been firstly developed for Sb removal via electrostatic self-assembly. The support matrix membrane contained iron nanocomposite (denoted as CIM) retained high water flux and porosity, and it reached a maximum removal capacity of 16.5 and 13.6 mg/g for Sb(III) and Sb(V) with nanofiller loading rate of 20% during static experiments, respectively. The coated SA top layer endowed the hybrid membrane (denoted as SA-CIM) to have a lower membrane flux, and have stronger retention abilities for Sb species than that by CIM during dynamic filtration experiments. The SA-CIM membranes also possess tolerable reversibility towards Sb removal. Benefiting from the negatively-charged dense selective layer and high adsorption capacity of the iron nanocomposites, the SA-CIM membranes demonstrated an enhanced removal capacity for Sb species via steric hindrance effect, electrostatic repulsion and adsorption. Our study offers a simple method to remove Sb by a novel polysaccharide functionalized hybrid membrane.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
