Abstract

Electrospinning, as a promising platform in multidisciplinary engineering over the past two decades, has overcome major challenges and has achieved remarkable breakthroughs in a wide variety of fields such as energy, environmental, and pharmaceutics. However, as a facile and cost-effective approach, its capability of creating nanofibers is still strongly limited by the numbers of treatable fluids. Most recently, more and more efforts have been spent on the treatments of liquids without electrospinnability using multifluid working processes. These unspinnable liquids, although have no electrospinnability themselves, can be converted into nanofibers when they are electrospun with an electrospinnable fluid. Among all sorts of multifluid electrospinning methods, coaxial electrospinning is the most fundamental one. In this review, the principle of modified coaxial electrospinning, in which unspinnable liquids are explored as the sheath working fluids, is introduced. Meanwhile, several typical examples are summarized, in which electrospun nanofibers aimed for the environment remediation were prepared using the modified coaxial electrospinning. Based on the exploration of unspinnable liquids, the present review opens a way for generating complex functional nanostructures from other kinds of multifluid electrospinning methods.

Highlights

  • Electrospinning, a simple and straightforward method for preparing nanofibers [1,2,3,4], is quickly moving forward along two important directions

  • As for the three-fluid processes, there are tri-axial process, coaxial process with a side-by-side core, side-by-side process with one coaxial side, and tri-layer parallel side-by-side one

  • These advanced techniques should greatly expand the capability of electrospinning in generating a wide variety of complex nanostructures

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Summary

Introduction

Electrospinning, a simple and straightforward method for preparing nanofibers [1,2,3,4], is quickly moving forward along two important directions. As for the three-fluid processes, there are tri-axial process (an abbreviation of tri-layer working fluids organized in a coaxial manner), coaxial process with a side-by-side core, side-by-side process with one coaxial side, and tri-layer parallel side-by-side one These advanced techniques should greatly expand the capability of electrospinning in generating a wide variety of complex nanostructures. The methods for creating core-sheath structures are always highly desired in scientific fields This should be one of the most important reasons that coaxial electrospinning [15,16], and coaxial electrospraying [17,18,19,20,21], are receiving the increasing attention nearly from all the applied functional material fields

The Modified Coaxial Electrospinning with an Unspinnable Sheath Fluid
The Nanofibers Prepared from Unspinnable Liquids for Environment Remediation
Findings
Conclusions and Perspectives
Full Text
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