Effect of UV Top Coating Microcapsules on the Coating Properties of Fiberboard Surfaces.

Abstract

The commonly used ultraviolet ray (UV) curing coatings have the characteristics of fast curing speed, high hardness, strong abrasion resistance, etc. However, the self-healing properties of UV coatings after being damaged still need to be improved. Self-healing microcapsules can alleviate this problem. The UV top coating itself has good properties, so it can be directly chosen as the core material of microcapsules. UV top coating microcapsules can be added to the UV top coating to increase the self-healing properties of the UV coating to achieve the purpose of better protection of the UV coating and fiberboards. UV top coating microcapsules were prepared and added in different contents to characterize the effect on the physical, chemical, and self-healing properties of the UV coating on a fiberboard surface. The 1#, 2#, and 3# UV top coating microcapsules that were prepared with emulsifier HLB values of 10.04, 10.88, and 11.72, respectively, were added to the UV top coating at contents of 2.0%, 4.0%, 6.0%, 8.0%, and 10.0%. The UV coatings were applied to the fiberboard using a method of two primers and two top coatings, in which no microcapsule was added in the primer, and were tested and analyzed. The results showed that when the content of microcapsules was greater than 6.0%, close to 8.0%, the excessive density of microcapsules produced stacking and extrusion between the microcapsules. As a result, the core material could not flow out smoothly when part of the microcapsule was ruptured. The outflow of the core material was not efficiently utilized, thus leading to a decrease in the self-healing rate. The 2# UV top coating microcapsules of 4.0% made the UV coatings reach the self-healing rate of 26.41%. The self-healing rate of the UV coatings prepared with the 3# UV top coating microcapsules with 6.0% was up to 26.58%. The UV coatings prepared with the 1# UV top coating microcapsules of 6.0% had the highest self-healing rate among the three groups, up to 27.32%. The UV coatings of this group had the best comprehensive properties with a chromatic aberration ΔE of 4.08, a gloss of 1.10 GU, a reflectance of 17.13%, an adhesion grade of 3, a hardness of 3H, a grade 3 of impact resistance, and a roughness of 1.677 μm. An investigation of the UV coatings on fiberboard surfaces with the content of UV top coating microcapsules can provide support for the optimization of the self-healing properties of UV coatings and can also provide innovative ideas for the preparation of the self-healing coatings on fiberboard surfaces.