Abstract

The electronic structure of La(Ni, Al, Co) 5 alloys has been studied by X-ray photoemission spectroscopy (XPS) and ab initio calculations based on linear muffin-tin orbitals (LMTO) method. Results showed that the substitution of Ni in LaNi 5 by Al and Co leads to some modifications of the electronic structure of the samples. We have found a good agreement between the experimental XPS valence band spectra and theoretical LMTO calculations.

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