Abstract
The absorption spectrum of Mn2+ doped in diglycine barium chloride monohydrate has been studied at room temperature. The observed bands are assigned as transitions from the 6A1g(S) ground state to various excited quartet levels of a Mn2+ ion in a cubic crystalline field. A new method has been suggested to evaluate the Racah parameters (B and C) accurately. The observed band positions are fitted with four parameters B, C, Dq and α, and the values obtained for the parameters are B= 810 cm-1, C = 2990 cm-1, Dq = 750 cm-1 and α = 76 cm-1.
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