Abstract
E.s.r. spectra are reported for a range of alkylsulphonyl and carbon-centred radicals detected during the oxidation of sulphoxides with the TiIII–H2O2 couple in aqueous solution. Alkylsulphonyl radicals are also formed in some cases by reaction of substituted alkyl radicals with SO2 in aqueous solution; however, hydroxy-conjugated radicals under these conditions behave as one-electron reducing agents and yield SO2– and carbonyl- and carboxy-conjugated radicals do not appear to react. Evidence is adduced for the ready desulphonylation of HO2C·CH2·SO2˙.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Perkin Transactions 2
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
