Electromagnetic dispersive solid-phase extraction based on polyaniline-coated magnetite/silica materials for the determination of Sudan red I in drinks.

Abstract

By replacing the permanent magnet with an electromagnet, traditional magnetic solid-phase extraction was developed into electromagnetic dispersive solid-phase extraction. A simple operation of power on and off can realize the separation of adsorbents from solutions easily. The improvement makes it possible for the automation of the determination of Sudan Red I by high-performance liquid chromatography. After series of optimization, a trace amount of Sudan red I was well-determined, and excellent linearity was achieved in the range of 0.005 to 1mg/L with the correlation coefficient (R2 )=0.997. The limit of detection with a signal-to-noise ratio of 3 was found to be 0.001mg/L. The spiked recoveries of Sudan red I for the samples ranged from 93.6 to 104.9%. Moreover, the adsorbent could be recycled at least ten times. The results show that the electromagnetic dispersive solid-phase extraction combined with high-performance liquid chromatography is a rapid, eco-friendly, effective, and sensitive determination method with fascinating automation potential and high practical applicability.