Abstract
Equations for the transition probability of non-adiabatic electron transfer are derived which take into account both the effect of reorganization of “non-symmetric” classical or quantum vibrational modes and the effects which are due to the dependence of the electron matrix element on the normal coordinates of “promoting” vibrational modes. Any number of vibrational modes with an arbitrary frequency spectrum are incorporated in a simple manner. The results are represented in a simple form convenient for the analysis of the dependence of the transition probability on the temperature, transfer distance, and driving force.
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