Effectiveness of chemical, mechanical and laser cleaning methods of sulphated black crusts developed on granite

Abstract

A study of the cleaning effectiveness of sulphated black crust developed on granite is presented. The sulphated black crust, previously characterized, was subjected to a cleaning by 1) a mechanical procedure –Hydrogommage– based on micro-sandblasting, 2) chemical procedures based on the application of poultices made on different mixes of thickening agents and cleaners and 3) laser cleaning using a 355nm Nd:YVO4 nanosecond laser. Chemical, mineralogical and physical characterization of the cleaned surfaces were performed; the global effectiveness as well as the harmfulness were evaluated according to the level of black crust removal and the substrate damages. As result, none of the methods has been completely effective in removing the sulphated black crust and, also, all the methods produced undesirable effects on the stone. The crust nature, its degree of interaction with the stone and other factors related to the principle of the cleaning procedures were found as the main variables influencing the effectiveness of the cleaning procedures.