Effect of welding state on the re-precipitation behavior of Cu-rich and NiAl nanoparticles in HAZ of 1100 MPa grade low carbon ultra-high strength steel

Abstract

The influence of multi-layer multi-pass welding and post-weld heat treatment (PWHT) on the co-precipitation behavior of Cu-rich and B2–NiAl, microstructural characteristics, grain size and mechanical properties of the coarse grain heat affected zone (CGHAZ) were systematically investigated for low-carbon ultra-high-strength steel with different Ni/Cu ratio. The results show that the CGHAZ microstructure of both high (1.5Cu) and low (2.0Cu) Ni/Cu ratio steel are composed of LB and GB, the grain size increases from 10.1 ± 1.1 μm and 9.5 ± 0.7 μm to 32.1 ± 1.0 μm and 32.2 ± 2.7 μm, and the nanoparticles are dissolved and subsequently re-precipitated during the welding process, with an average radius 1.56 nm and 1.71 nm, respectively. The hardness profile of the joint shows softening at CGHAZ and the tensile strength reaches 1218 MPa and 1056 MPa respectively. After PWHT, the re-precipitated behavior of the nanoparticles was enhanced, with average radius of 1.53 nm and 1.55 nm, and the number density increases from 1.55 × 1023 m−3 and 1.06 × 1023 m−3 to 4.01 × 1023 m−3 and 3.33 × 1023 m−3, respectively. The co-precipitation evolution mechanism shows that the typical core-shell structure is transformed into individual 9 R–Cu and B2–NiAl particles, and a large number of small-sized B2–NiAl particles were re-precipitated during the aging process. The strengthening mechanism shows that martensite strengthening and grain size strengthening are weakened in the as-welded CGHAZ, and only part of the nanoparticles was re-precipitated leading to the softening of CGHAZ during welding. After PWHT, a large number of small-sized nanoparticles were re-precipitated to restore the contribution of precipitation strengthening, while small-sized nanoparticles interacted with dislocations and entangled near the M-A constituents to promote the formation of microvoids and microcracks, thus seriously deteriorating the ductility.