Abstract

In this paper, effect of soldering time and temperature on formation of intermetallic compounds developed between Sn–0.3Ag–0.7Cu lead-free solder and copper substrate was investigated. Dip soldering was performed at 250, 270, and 290 °C with soldering time of 5, 10, 15, and 20 s. Either ɛ-Cu 3Sn or η-Cu 6Sn 5 intermetallic phase was found at the interface between the solder and the substrate depending on the soldering condition, i.e., soldering time and soldering temperature. ɛ-Cu 3Sn was found only when the substrate was soldered at 250 °C for 5 and 10 s. At other soldering conditions, only η-Cu 6Sn 5 was found at the interfacial zone. Crystal structure of ɛ-Cu 3Sn intermetallic phase was orthorhombic, and it was hexagonal structure for η-Cu 6Sn 5. Transformation of the intermetallic phases was also discussed.

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