Effect of Sm and Fe co-doping on structural, dielectric and magnetic properties of YCrO3 perovskite

Abstract

In this report, impact of co-doping of samarium (Sm3+) and iron (Fe3+) on structural, dielectric and magnetic properties of YCrO3 compound has been investigated. Here, YCrO3 and Y1-xSmxCr1-yFeyO3 (x = 0.3, y = 0.1) compounds are synthesized successfully through sol–gel auto combustion route. The synthesized samples are characterized through X-ray diffraction (XRD), surface electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), impedance analyzer and vibrating sample magnetometer (VSM) techniques. Rietveld refinement of XRD analysis reveals that both the compounds are crystallized in distorted orthorhombic structure belongs to Pnma space group. It is observed that with co-doping of both Sm3+ and Fe3+, lattice unit cell volume increases. SEM micrograph shows that the grains are slightly elongated as compared to the undoped sample. The temperature variation of real part of dielectric permittivity (εr) and tangent loss (tan δ) are analyzed over a frequency range 40 KHz − 500 KHz at a temperature range 300 K − 523 K. The temperature dependent dielectric permittivity reveals that both εr and tan δ decrease with co-doping. Moreover, both the compounds show relaxor like ferroelectric transition. Room temperature field dependent magnetization analysis shows that maximum magnetization value increases with co-doping. The result reveals that the enhanced properties with co-doping can be useful for practical device applications.