Abstract
The volumetric method originally developed for the determination of the sticking probabilities of adsorption or absorption reactions of hydrogen, nitrogen and oxygen with pure metals can also be used to determine the kinetics of more complex metal-gas reactions if appropriate changes in the experimental technique and in formulae for data evaluation are made. The modifications necessary are discussed and some typical results are presented. These are the hydrogen absorption of titanium and FeTi films with and without oxygen precoverage and of a Ti-Pd sandwich with oxygen precoverage, and the reaction of H 2O with an iron film.
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