Abstract
Isopropanolic Suspensions of HA nanoparticles (20 g/L) plus various concentrations of carbon nanotubes (CNTs) were prepared using Tris and triethanolamine as dispersant. The positively charged HA nanoparticles were heterocoagulated on the negatively charged CNTs and generated the HA‐CNT composite particles with net positive surface charge. The heterocoagulation was more intensive in dispersant‐containing suspensions (DCS) due to the higher zeta potential of HA nanoparticles in them. HA‐CNTs particles can be rotated and aligned parallel to electric field as a result of torque exerted on them due to the generation of a dipole moment in CNTs during electrophoretic deposition (EPD). The mobility of HA‐CNTs particles aligned parallel to electric field is ≈50% higher than that of HA nanoparticles leading to the faster EPD from DCS when CNTs are added into them. CNTs more efficiently reinforced the coatings deposited from DCS due to the stronger electrostatic bonding between CNTs and HA nanoparticles in them.
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