Abstract
Two mononuclear DyIII complexes [Dy(H2TEG)(NO3)3]·[18-crown-6] (H2TEG=triethylene glycol) (1) and [Dy(H2TEG)Cl3]·[18-crown-6] (2) have been prepared using H2TEG as ligands. Magnetic studies revealed that both complexes show field-induced double magnetic relaxation behavior with energy barriers of 28K and 54K. Distinct magnetic dynamic properties observed in 1 and 2 are mostly attributed to the dissimilar coordination environments around DyIII centers in these two complexes.
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