Eco-Friendly Methanolic Myrrh Extract Corrosion Inhibitor for Aluminum in 1 M HCl.

Abstract

Aluminum corrosion was inhibited by myrrh extract when it was placed in a solution of 1 M HCl. Several procedures were used for these tests, including weight loss WL, potential dynamic polarization PL, and electrochemical impedance EIS in addition to theoretical calculations like density functional theory (DFT), Fukui functions, and Monte Carlo simulation. Fourier transform infrared spectroscopy was used to analyze the compositional surface of Al. Scanning electron microscopy was used to determine the shape of the Al surface. The inhibition rate of Al corrosion in HCl with varying myrrh extract contents at 25-45 °C was studied. An analysis of the PL curves indicates that myrrh extract is an inhibitor of mixed type. Upon increasing the concentration of myrrh, the inhibition efficiency increased. Moreover, rising temperatures decrease inhibition efficiency. It was discovered that the inhibition process follows the Langmuir isotherm, demonstrating that a monolayer has formed on the surface of aluminum. Theoretical and practical studies proved the validity of the conclusions.