Corrosion Prevention of Copper in 2.0 M Sulfamic Acid Using Novel Plant Extract: Chemical, Electrochemical, and Theoretical Studies.

Abstract

Copper corrosion was suppressed when a lupine extract was immersed in a 2 M sulfamic acid (H2NSO3H) solution. Numerous methods, including mass loss (ML), dynamic potential polarization (PL), and electrochemical impedance (EIS), were employed in these experiments, in addition to theoretical computations such as density functional theory (DFT), Fukui function, and Monte Carlo simulations. Fourier transform infrared (FT-IR) spectroscopy and scanning electron microscopy (SEM) were used to analyze the Cu surface's composition and determine its form. Mass loss (ML) was used to examine the inhibition rate of copper corrosion in sulfamic acid at 25 °C in the presence of lupine extract. After examining how it behaved throughout the adsorption process on copper, it was discovered that it follows the Langmuir isotherm and chemical adsorption. An analysis of the PL curves indicates that the lupine extract is a mixed-type inhibitor. It was shown that the inhibitory efficiency increased to 84.2% with increasing lupine concentration. Additionally, as the data show, the efficiency of inhibitors is diminished by increasing temperatures. Theoretical calculations and experimental data were compared using Monte Carlo simulation (MC) and density functional theory (DFT).