Abstract
In this study, in order to develop low-temperature-sintering ceramics for a multilayer piezoelectric actuator, Pb(Mg1/2W1/2)O3-Pb(Ni1/3Nb2/3)O3-Pb(Zr,Ti)O3 (PMW-PNN-PZT) ceramics were fabricated using Li2CO3 and CaCO3 as sintering aids and their dielectric and piezoelectric properties were investigated in relation to the amount of Bi substitution. Piezoelectric actuators require both a high piezoelectric constant (d33) and a high electromechanical coupling factor (kp). Accordingly, in this study, Bi was substituted at the Pb site of basic composition PMW-PNN-PZT ceramics for the enhancement of kp and d33. With increasing Bi substitution, density gradually increased. At the sintering temperature of 900°C, the electromechanical coupling factor (kp) and piezoelectric constant (d33) of PMW-PNN-PZT composition ceramics with 1.0 mol % Bi substitution as well as 0.2 wt % Li2CO3 and 0.25 wt % CaCO3 showed the optimal value of 0.618 and 473 pC/N, respectively, for multilayer piezoelectric actuator application.
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